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The scanning tunneling microscope (STM), invented at the IBM Zurich Research Laboratory in 1981, was an almost-instant success. Its inventors, Heinrich Rohrer and Gerd Binnig, had to wait only five years before they were awarded the Nobel Prize alongside Ernst Ruska, who had had to wait 53 years since inventing the electron microscope. The STM's quick appeal stemmed from early images of individual adatoms resting on a well-known and famously puzzling semiconductor surface, the so-called silicon (111) 7 × 7. Thus, surface scientists were (and are) an important constituency for STM. However, Binnig and Rohrer eagerly adapted the STM for other disciplines such as biophysics and electrochemistry.

Through this broadening of its appeal, the STM became the parent instrument for a wide variety of scanning probe techniques. In the early 1990s, biophysical STM suffered a setback when claims for atomic resolution of DNA were called into question. However, 1990 also saw STM's greatest triumph when Don Eigler and Erhard Schweizer used an STM tip to position 35 xenon atoms on a nickel surface to spell out “I-B-M.” This and other STM images offered powerful public legitimation for nanotechnology proponents, in that they offered a proof of principle that humans could visualize and even interact with nanoscale objects.

A Sideshow Becomes the Main Event

The STM arose from a multimillion-dollar IBM project to develop a supercomputer based on superconducting (rather than semiconducting) logic elements. Researchers on the project had trouble making thin oxide films and asked a colleague at the IBM Zurich laboratory, Heinrich Rohrer, to investigate. Rohrer put a newly hired physicist, Gerd Binnig onto the task. Together, they decided to develop a new kind of instrument based on electron tunneling, rather than try to understand the problem using existing instruments. Their “tunneling microscope” consisted of a sharp metal or semiconductor probe, which approached a metal or semiconductor sample to within a few angstroms (0.1 nanometer or 1 × 10−10 meters), at which point electrons would “tunnel” between probe and sample. Tunneling is a quantum phenomenon in which there is a finite probability that a particle's waveform will collapse in one region and re-form in another region without having to surmount the energy barrier between those regions (like moving through a wall without having to break the bricks).

A Community Forms

This instrument became a microscope when Binnig and Rohrer moved the tip back and forth, recording the strength of the tunneling current as it passed over a matrix of points on the sample. By the time they accomplished this, though, the supercomputer project was winding down. So they consulted IBM colleagues to see what other samples to look at. Some surface scientists suggested the silicon (111) 7 × 7, an intriguing surface in which the silicon atoms arrange in a then-unknown pattern. When Binnig and Rohrer published images of single atoms of the 7 × 7 in 1983, the STM quickly catapulted to the wider scientific community's attention. Though they did not solve the mystery of the 7 × 7 themselves, their work on it won Binnig and Rohrer the 1986 Nobel Prize in physics, and spurred many surface scientists and others to build their own STMs.

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