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Air Quality

The standard composition of a well-mixed atmosphere is approximately 78 percent nitrogen, 21 percent oxygen, 0.93 percent argon, and 0.038 percent carbon dioxide, plus water vapor (spatially and temporally variable) and numerous trace constituents. Because of the negative impacts of poor air quality, such as acid precipitation or compromised human health, an understanding of both normal and disturbed atmospheric conditions is necessary. Air quality is an assessment of the state of the atmosphere that uses a combination of various characteristics describing the ambient atmosphere, including concentration of pollutants, visibility, turbidity, and thermal pollution. Air quality problems are often common to urbanized regions, where people engage in industrial activities, vehicular traffic is concentrated, and other conditions that deteriorate the ambient atmosphere exist. Efforts to mitigate compromised air quality range from international treaties and protocols to local regulations and ordinances.

Photochemical smog, most commonly associated with Los Angeles, is caused by the interaction of solar radiation with pollutants like nitrogen oxides, peroxyacytyl nitrate, and volatile organic compounds

Source: iStockphoto

Pollutants that compromise the “clean” characteristics of the air may come from nonhuman or human (anthropogenic) sources. Nonhuman sources of pollutants include volcanic eruptions, which send ash and sulfurous gases into the atmosphere, diminishing local visibility and possibly contributing to cooling on a global scale. Lightning-caused forest fires create airborne particulates, or soot, and anaerobic decomposition in wetlands is a source of methane. Because there is little that can be done with respect to natural sources of air pollutants, efforts to restore and maintain air quality usually focus on reducing anthropogenic sources of pollution. Anthropogenic sources of air pollutants include particulate matter caused by combustion engines, chemicals released by industrial and agricultural processes, and the use of consumer products.

Components of Air Quality

Increasing the concentrations of pollutants compromises the integrity of the ambient air and causes human health problems. Sulfur dioxide, for example, affects the respiratory and circulatory systems of humans, with particularly sensitive populations (e.g., the elderly, asthmatics, children) suffering the most. Carbon monoxide can impair the transport of oxygen to the brain and other organs. Toxic chemicals in the air can cause a range of adverse health problems.

Another component of air quality is visibility, or the ability to view objects at a distance. Visibility is described as the farthest horizontal distance at which the unaided eye can view an object. Atmospheric substances can impair visibility, reducing the visual quality of the air. Particulates may reflect or scatter solar radiation, which decreases viewing ability. Smog, largely produced by coal combustion, as well as by industrial and vehicular emissions that interact with incoming sunlight, reduces visibility. Haze, another cause for diminished visibility, is also caused by air pollution.

Turbidity refers to a reduction in the cloud-free part of the atmosphere's ability to transmit light. It is a function of both atmospheric depth (measured in the vertical) and the components in the air. In the troposphere, turbidity is typically caused by anthropogenic activities and can be described by Beer's Law. Turbidity is both spatially and temporally variable. An urban megalopolis, for example, typically exhibits greater turbidity than a proximate rural locale, owing to the greater presence of aerosols, tropospheric ozone, and other factors. Turbidity is not to be confused with global dimming—a phenomenon describing the overall reduced amount of solar radiation striking the Earth's surface.

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