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Thallium
Thallium (Gr. thallos, a green shoot or twig, Tl; at. wt. 204.3833(2); at. no. 81) is treated as a hazardous substance. Sir William Crookes discovered thallium spectroscopically in 1861. The metal is very soft and malleable and can be cut with a knife. Forty-seven isotopic forms of thallium, with atomic masses ranging from 179 to 210, are recognized.
It is not a rare element—for instance, it is 10 times more abundant than silver. In natural deposits as ores, thallium is found together with other elements. One of the biggest natural deposits is located in Macedonia. The element is widely dispersed in potassium minerals, such as sylvite and pollucite. Thallium minerals are rare, but a few are known, such as crookesirte and lorandite. Man-made sources of thallium pollution are gaseous emissions of cement factories, coal-burning power plants, and metal sewers. The leaching of thallium from oreprocessing operations is the major source of elevated thallium concentrations in water. Thallium is a trace metal associated with copper, gold, zinc, and cadmium. Thallium does not long persist if released to water, but does have a strong tendency to accumulate in aquatic life. If released to land, it may bind to alkaline soils but may otherwise migrate to groundwater. Thallium occurs in small amounts in almost all living organisms.
World production of thallium compound is around 30 tons per year. Thallium has not been produced in the United States since 1984. There has been no assessment of the size of reserves.
Consumption and Health
The greatest use of this metal is in specialized electronic research equipment (electronic devices, switches, and closures, primarily for the semiconductor industry). It also has limited use in the manufacture of special glass and for certain medical procedures.
Thallium is toxic and does not have any positive effect on people's health if consumed through food and water or absorbed in larger quantity from the atmosphere. Recent research in China, for instance, shows that thallium concentration in plants exhibits species-dependent preferences, decreased from green cabbage toward corn. The highest level of Tl in green cabbage is up to 500 milligrams (mg)/kilogram (kg) as dry weight, surpassing the values of Tl in the soils in which the green cabbages grow.
The Maximum Contaminant Level Goals (MCLG) for thallium in water set by the Environmental Protection Agency (EPA) is 0.5 parts per billion (ppb), while the enforceable standard called a Maximum Contaminant Level (MCL) is set at 2 ppb. Short-term health effects of the thallium consumed above MCL may include gastrointestinal irritation and nerve damage, and long-term changes in blood chemistry, damage to liver, kidney, intestinal and testicular tissues, polyneuropathy, visual impairment, hair loss, and even death.
The Occupational Safety and Health Administration (OSHA) has set an exposure limit of 0.1 mg per cubic meter (0.1 mg/M3) for thallium in workplace air. The National Institute for Occupational Safety and Health (NIOSH) has recommended that 15 mg/M3 of thallium be considered immediately dangerous to life and health. This is the exposure level of a chemical that is likely to cause permanent health problems or death.
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