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Rubber is a polymer that, when strengthened through the process of vulcanization, becomes a thermoset elastomer characterized by desirable properties, including flexibility, durability, and impact resistance, and which has many industrial uses. Natural rubber is derived from latex, a milky substance produced from several plants but most commonly obtained from the para rubber tree (Hevea brasiliensis). Rubber has been known to Western science since the 18th century but commercial exploitation greatly increased in the late 19th century as rubber trees were successfully cultivated in southeast Asia and later Africa. Creating natural rubber involves tapping the trees for latex (containing about 70 percent water), which is then sieved for impurities, blended, coagulated, and dried in smokehouses or in deep-bed dryers.

Michael Faraday described the molecular structure of rubber in 1826, but it was not until the early 20th century that synthetic rubber was created, partly in response to increased demand (and thus higher prices) for natural rubber. Today, over 200 types of synthetic rubber are manufactured, all involving polymerization of one or more monomers, most of the latter being derived from oil. The most common type of synthetic rubber, styrene butadiene rubber (SBR), accounts for about 37 percent of synthetic rubber created in the world. SBR is created from two monomers, styrene and butadiene, which are polymerized in the presence of a catalyst, and the resulting polymer is coagulated, washed, filtered, and dried.

Vehicle Tires

Almost 60 percent of rubber consumed globally is used by the tire manufacturing industry, and the disposal of rubber tires used in automobiles and other vehicles is a serious problem in much of the world. In the United States in 2003, 290 million scrap tires were disposed of, constituting 2 percent of total solid waste. Whole tires are problematic in landfills because of the large amount of empty space contained within a tire, which not only increases the volume of space required but can also trap gases and offers breeding grounds for rodents and (if filled with water) mosquitoes. For this reason, tires are sometimes shredded before being added to landfills. As of 2003, 38 U.S. states banned whole tires from landfills and 11 banned all tires from landfills, while 35 states allowed only shredded tires to be placed in landfills. Aggressive cleanup and scrap tire management programs in many U.S. states have substantially reduced the number of scrap tires in landfills and other stockpiles, from 700–800 million in 1994 to 275 million in 2004.

In many states, tires are classified as either hazardous waste or special waste, in either case requiring a permit to dispose of them. This has led to illegal dumping, which creates many hazards, including ground and water pollution and creation of breeding grounds for pests. Incineration of discarded tires is not practical because when burned, tires break down into hazardous compounds, including oil, heavy metals, and gases: a passenger tire typically produces more than two gallons of oil when burned. This oil may seep into the ground and require environmental cleanup.

Tire fires, although relatively rare, pose significant environmental risk by releasing pollutants such as polycyclic aromatic hydrocarbons, benzene, styrene, phenols, and butadiene into the air. Tire fires can also be quite difficult and expensive to extinguish and may require evacuation of surrounding communities. For instance, a 1983 tire fire in Rhinehart, Virginia, burned for almost nine months, depositing air pollution in three states, polluting water sources with lead and arsenic, and requiring cleanup as a Superfund site. A 1999 tire fire in Westley, California, required intervention by the Environmental Protection Agency (EPA) and took 30 days to extinguish at a cost of about $3.5 million.

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